Investigation and Review of the Capping Method of Contaminated Sediments in Aquatic Ecosystems Using Activated Carbon

Authors
1 MSc in Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Qom, Iran
2 MSc in Chemical Engineering, Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Iran
Abstract
Effective and safe treatment of contaminated sediments in aquatic ecosystems has always been one of the most important environmental challenges in the world. Natural ecosystems are always threatened by likely accumulation of toxic pollutants. Therefore, rapid remediation of these valuable ecosystems is essential. Dredging and Capping are among the well-known methods in the world that have been used for clean and quick reduction of the concentration of toxic contaminants in sediments. Capping is a proven and common remediation technology for containment of contaminated sediments in order to reduce their contaminants mobility and contact with the environment. In capping, the contaminated sediments are covered by one or more layers of clean materials such as sand, gravel, clean dredged material, active or reactive materials and etc. This method provides the restoration of these ecosystems by rapidly reducing the amount of pollutants in surface waters through absorbing and reducing the mobility of toxic substances in contaminated sediments. This technology has less environmental hazards than the dredging method, while it has never been studied on a laboratory or field scale in Iran. This research intends to introduce the method involving activated carbon, as a background for the implementation of this technology in the country. This research is of practical type and documentary-libraries in terms of purpose and method of data collection, respectively.
Keywords

حقشناس، آ. حاتمی‌منش، م. میرزائی، م. میرسنجری، م. و حسین‌خضری، پ. 1396. سنجش و ارزیابی خطر اکولوژیکی فلزات سنگین در رسوبات سطحی منطقه ویژه اقتصادی انرژی پارس. دوماهنامه طبّ جنوب، دوره 20، شماره 5.
کرباسی، ع. و شادی، ر. 1391. ارزیابی اثرات محیط زیستی طرح‌های لایروبی. اولین همآیش ملی توسعه سواحل مکران و اقتدار دریایی جمهوری اسلامی ایران. دانشگاه دریانوردی و علوم دریایی چابهار، منطقه سوم نیروی دریایی راهبردی ارتش جمهوری اسلامی ایران-کنارک.
Cornelissen, G.; Breedveld, G. D.; Naes, K.; Oen, A. M. P. & Ruus, A. 2006. Bioaccumulation of native polycyclic aromatic hydrocarbons from sediment by a polychaete and a gastropod: Freely dissolved concentrations and activated carbon amendment. Environ. Environmental Toxicology and Chemistry, 25(9): 2349–2355.
Ghosh, U.; Luthy, R.G.; Cornelissen, G.; Werner, D. & Menzie, C. 2011. In situ Sorbent Amendments: A New Direction in Contaminated Sediment Management. Environmental Science & Technology, 45(4): 1163 – 1168.
ITRC, (Interstate Technology & Regulatory Council). 2014. Contaminated Sediments Remediation. CS-2. Washington, D.C.: Interstate Technology & Regulatory Council, Contaminated Sediments Team.
Jersak, J.; Göransson, G.; Ohlsson, Y.; Larsson, L.; Flyhammar, P. & Lindh, P. 2016. In-situ capping of contaminated sediments. Method overview. SGI Publication 30-1E, Swedish Geotechnical Institute, SGI, Linköping.
Knox, A. S.; Paller, M. H.; Reible, D. D.; Ma, X. & Petrisor, I. G. 2008. Draft Sequestering Agents for Active caps – Remediation of Metals and Organics. Prepared under contract No. DE-AC09-96SR18500 with the Department of Energy.
Kupryianchyk, D.; Rakowaka, M.; Roessink, I.; Reichman, E.P.; Grotenhuis, J. T. C. & Koelmans, A. A. 2013. In situ treatment with activated carbon reduces bioaccumulation in aquatic food chains. Environmental Science & Technology, 47 (9): 4563–4571.
Lampert, D. J. & Reible, D. 2009. An Analytical Modeling Approach for Evaluation of Capping of Contaminated Sediments. Soil and  Sediment Contamination: An International  Journal, 18(4): 470 – 488.
Murphy, P.; Marquette, A.; Reible, D. & Lowry, G. V. 2006. Predicting the Performance of Sediment Caps Amended with Sorbing Media. Journal of Environmental Engineering, 132:787-794.
Menzie, C.A. 2012. "SediMite®A Delivery System for Amending Contaminated Sediment with Activated Carbon and/or other Amendments." Prepared for Lower Duwamish Waterway Workshop. February.
Millward, R. N.; Bridges, T. S.; Ghosh, U.; Zimmerman, J. R. & Luthy, R. G. 2005. Addition of activated carbon to sediments to reduce PCB bioaccumulation by a polychaete (Neanthes arenaceodentata) and an amphipod (Leptocheirus plumulosus). Environmental Science & Technology, 39(8): 2880-2887.
Menzie, C. 2016. A Low-Impact Delivery System for In Situ Treatment of Sediments Contaminated with Methyl Mercury and other Hydrophobic Chemicals. ER-200835.
Olsta, J.T. & Darlington, J. 2005. Innovative Systems for Dredging, Dewatering, or for In-situ Capping of Contaminated Sediments. The 21st Annual International Conference on Soils, Sediments, and Water. University of Massachusetts at Amherst. October 17 through 20.
Patmont, C. R.; Ghosh, U.; LaRosa, P.; Menzie, C.; Luthy, R. G.; Greenberg, M. S.; Cornelissen, G.; Eek, E.; Collins, J;  Hull; J.; Hjartland, T.; Glaza, E.; Bleiler, J. & Quadrini, J. 2015. In situ sediment treatment using activated carbon: A demonstrated sediment cleanup technology. Integrated Environmental Assessment and Management, 11(2): 195–207.
Palermo, M.; Maynord, S.; Miller, J. & Reible, D. 1998. Guidance for In-Situ Subaqueous Capping of Contaminated Sediments. EPA 905-896-004. Great Lakes National Program Office, Chicago, IL.
Parsons, & Anchor QEA. 2012b. Onondaga Lake Capping, Dredging, Habitat and Profundal Zone (SMU 8) Final Design. Appendix B –Cap Modeling. https://www.dec.ny.gov/docs/regions_pdf/prof2.pdf.
Reible, D. 2004. In Situ Sediment Remediation Through Capping: Status and Research Needs. Hazardous Substance Research Center/South and Southwest. 20 pages.
Sun, X. & Ghosh, U. 2008. The Effect of Activated Carbon on Partitioning, Desorption, and Biouptake of Native Polychlorinated Biphenyls in Four Freshwater Sediments. Environmental Toxicology and Chemistry, 27(11): 2287-2295.
Sowers, K. R.; Ghosh, U. & May, H. D. 2018. Evaluating the Efficacy of Bioaugmentation for In-Situ Treatment of PCB Impacted Sediments. Final Technical Report, ESTCP Project ER-201215.
Schaanning, M. T.; Beylich, B.; Gunnarsson, J. S. & Eek, E. 2021. Long-term effects of thin layer capping in the Grenland fjords, Norway: Reduced uptake of dioxins in passive samplers and sedimentdwelling organisms. Chemosphere, 264(2): 1-11.
USEPA, 1997. Guiding Principles for Monte Carlo Analysis. Risk Assessment Forum. U.S.Environmental Protection Agency, EPA/630/R-97/001.
USEPA, 2004c. Guidance for Monitoring at Hazardous Waste Sites: Framework for Monitoring Plan Development and Implementation. U.S. Environmental Protection Agency’s (EPA’s) new “Monitoring Guidance,” OSWER  9355.4-28.
USEPA, 2005. Contaminated Sediment Remediation Guidance for Hazardous Waste Sites. EPA-540-R-05-012 OSWER 9355.0-85.
USEPA, 2013. Use of Amendments for In Situ Remediation at Superfund Sediment Sites. Office of Superfund Remediation and Technology Innovation.
Zimmerman, J. R.; Ghosh, U.; Millward, R. N.; Bridges, T. S. & Luthy, R. G. Addition of carbon sorbents to reduce PCB and PAH bioavailability in marine sediments: Physicochemical tests. Environmental Science & Technology, 38(20): 5458–5464.
AquaBlok, Ltd. 2019. AquaGate+ for Contaminated Sediments. Retrieved from: https://www.aquablok.com/ remediation/products/aquagate.
Parsons, 2004. Onondaga lake feasibility study report. Retrieved from: http://www.lakecleanup.com/ publicdocs/docs.
SSC, (Sediment Solutions Corporation). 2020. Spec. Sheet of SediMiteR, Retrieved from: http:// www.sedimite.com/specs.